36

Chiang, K.P.; Barrett, P.M.; Ding, F.; Smith, J.M.; Kingsley, S.; Brennessel, W.W.; Clark, M.M. Lachicotte, R.J.; Holland, P.L. “Ligand Dependence of Binding to Three-Coordinate Fe(II) Complexes” Inorg. Chem. 2009, 48, 5106-5116.

35

Stoian, S.A.; Smith, J.M.; Holland, P.L.; Münck, E.; Bominaar, E.L. “Mössbauer, EPR and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex” Inorg. Chem. 2008, 47, 8687-8695.

34

Yu, Y.; Sadique, A.R.; Smith, J.M.; Dugan, T.R.; Cowley, R.E.; Brennessel, W.W.; Flaschenriem, C.J.; Bill, E.; Cundari, T.R.; Holland, P.L. “The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes” J. Am. Chem. Soc. 2008, 130, 6624-6638.

33

Vela, J.; Cirera, J.; Smith, J.M.; Lachicotte, R.J.; Flaschenriem, C.J.; Alvarez, S.; Holland, P.L. “Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes” Inorg. Chem., 2007, 46, 60-71.

32

Stoian, S.; Vela, J.; Smith, J.M.; Holland, P.L.; Münck, E.; Bominaar, E.L. “Mössbauer and Computational Study of an N2-Bridged Diiron(I) Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen” J. Am. Chem. Soc., 2006, 128, 10181-10192.

31

Bourgeois, C.J.; Garratt, S.A.; Hughes, R.P.; Laritchev, R.B.; Smith, J.M.; Ward, A.J.; Zhang, D.; Zakharov, L.N.; Rheingold, A.L. “Synthesis and Structural Characterization of Perfluoroalkyl(fluoro)iridium(III) and Perfluoroalkyl(methyl)iridium(III) Compounds” Organometallics, 2006, 25, 3474-3480.

30

Yu, Y.; Smith, J.M.; Flaschenriem, C.J.; Holland, P.L “Binding Affinity of Unsaturated Ligands in Low-Coordinate Iron(I) Complexes” Inorg. Chem., 2006, 45, 5742-5751. (featured on the July 24, 2006 cover of Inorg. Chem.)

29

Smith, J.M.; Sadique, A.R.; Cundari, T.R.; Rodgers, K.R.; Lukat-Rodgers, G.; Lachicotte, R.J.; Flaschenriem, C.J.; Vela, J; Holland, P.L. “Studies of Low-Coordinate Iron-Dinitrogen Complexes”, J. Am. Chem Soc., 2006, 128, 756-769.

28

Bourgeois, C.J.; Hughes, R.P.; Husebo, T.L.; Smith, J.M.; Guzei, I.M.; Liable-Sands, L.M.; Zakharov, L.N.; Rheingold, A.L. “Reactions of Perfluoroalkyl Iodides with M(C5H5)(CO)(PMe3) [M = Rh, Ir]; Evidence for Direct Fluoroalkylation at a CO Ligand”, Organometallics, 2005, 24, 6431-6439.

27

Eckert, N.A.; Stoian, S.; Smith, J.M.; Lachicotte, R.J.; Münck, E.; Holland, P.L.; “Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex.”, J. Am. Chem. Soc., 2005, 127, 9344-9345.

26

Stoian, S.; Smith, J.M.; Yu, Y.; Bominaar, E.L.; Holland, P.L.; Münck, E. “Mössbauer, EPR and Crystallographic Characterization of a High-spin Fe(I) Diketiminate Complex with Orbital Degeneracy”, Inorg. Chem., 2005, 44, 4915-4922.

25

Vela, J.; Smith, J.M.; Yu, Y.; Ketterer, N.A.; Flaschenriem, C.J.; Lachicotte, R.J.; Holland, P.L. “Synthesis and Reactivity of Low Coordinate Iron(II) Fluorides, and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons”, J. Am. Chem. Soc., 2005, 127, 7857-7870.

24

Vela, J.; Vaddadi, S.; Cundari, T.R.; Smith, J.M.; Gregory, E.A.; Lachicotte, R.J.; Flaschenriem, C.J.; Holland, P.L. “Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies.”, Organometallics 2004, 23, 5226-5239.

23

Eckert, N.A.; Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Low-Coordinate Fe(II) Amido Complexes of b-Diketiminates: Synthesis, Structure and Reactivity.”, Inorg. Chem., 2004, 43, 3306-3321.

22

Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “N=N Bond Cleavage by a Low Coordinate Iron(II) Hydride Complex.”, J. Am. Chem. Soc., 2003, 125, 15752-15753.

21

Vela, J.; Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Alkyl Isomerisation in Three-Coordinate Iron(II) Complexes.”, Chem. Commun., 2002, 2886-2887.

20

Pelczar, E.M.; Nytko, E.A.; Zhuravel, M.; Smith, J.M.; Glueck, D.S. “Synthesis and Structure of Platinum and Palladium Complexes of Dimesitylphosphine.”, Polyhedron, 2002, 21, 2409-2419.

19

Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Three-Coordinate, 12-Electron Organometallic Complexes of Iron(II) Supported by a Bulky b-Diketiminate Ligand: Synthesis and Insertion of CO to give Square Pyramidal Complexes.”, Organometallics, 2002, 21, 4808-4814.

18

Hughes, R.P.; Smith, J.M.; Incarvito, C.D.; Lam, K.-C.; Rhatigan, B.; Rheingold, A.L. “Cationic Iridium-Perfluoroalkyl Complexes with NH3 and PH3 Ligands. Activation of Carbon-Fluorine Bonds by H2S to Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes.”, Organometallics, 2002, 21, 2136-2144.

17

Andres, H.; Bominaar, E.L.; Smith, J.M.; Eckert, N.A.; Holland, P.L.; Münck, E. “Planar Three-Coordinate High-Spin FeII Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies.”, J. Am. Chem. Soc., 2002, 124, 3012-3025.

16

Smith, J.M.; Lachicotte, R.J.; Rogers, K.R.; Lukat-Rogers, G.; Pittard, K.A.; Cundari, T.R.; Holland, P.L. "Stepwise Reduction of Dinitrogen Bond Order by a Low Coordinate Iron Complex.", J. Am. Chem. Soc. 2001, 123, 9222-9223.

15

Smith, J.M.; Lachicotte, R.J.; Holland, P.L “Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex.”, Chem. Commun. 2001, 1542-1543.

14

Hughes, R.P.; Lindner, D.C.; Smith, J.M.; Zhang, D.; Incarvito, C.; Lam, K.-C.; Liable-Sands, L.M.; Sommer, R.; Rheingold, A.L. “Water, water, everywhere. Synthesis and structures of perfluoroalkyl rhodium and iridium(III) compounds containing water ligands.”, J. Chem. Soc., Dalton Trans. 2001, 2270-2278.

13

Hughes, R.P.; Kovacik, I.; Lindner, D.C.; Smith, J.M.; Willemsen, S.; Zhang, D.; Guzei, I.A.; Rheingold, A.L. “Unusual Reactivity of 'Proton Sponge' as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III).”, Organometallics 2001, 20, 3190-3197.

12

Smith, J.M.; Coville, N.J. “Steric Parameters of Conformationally Flexible Ligands from X-ray Structural Data. 2. P(OR)3 Ligands in Multiple Ligand Environments.”, Organometallics 2001, 20, 1210-1215.

11

Grimmer, N.E.; Coville, N.J.; de Koning, C.B.; Smith, J.M.; Cook, L.M. “Zirconium bis-indenyl compounds. Synthesis and X-ray crystallography study of 1- and 2-substituted bis(R-indenyl)zirconium dichloride metallocenes.”, J. Organomet. Chem. 2000, 616, 112-127.

10

Smith J.M.; Coville, N.J.; Cook, L.M.; Boeyens, J.C.A. “Steric Parameters of Conformationally Flexible Ligands from X-ray Structural Data. 1. P(OR)3 Ligands in Equivalent Ligand Environments.”, Organometallics 2000, 19, 5273-5280.

9

Smith, J.M.; Cheng, L.; Schulte, J.; Dimpe, P.S.; Adsetts, M.S.; Coville, N.J.; Cook, L.M.; Boeyens, J.C.A.; Levendis, D.C. “Solid State Reactivity and Crystal Structure Studies. The Case of diag-lat Isomerization in [Re(h5-C5H4Me)(CO)(P(OPh)3)Br2] and [Re(h5-C5H4tBu)(CO)2Br2].”, Organometallics 2000, 19, 2597-2602.

8

Hughes, R.P.; Smith, J.M.; Liable-Sands, L.M.; Concolino, T.E.; Lam, K.-C.; Incarvito, C.; Rheingold, A.L. “Syntheses and X-ray crystallographic study of [Ir(h5-C5Me5)(L)(RF)I] (L = CO, PMe3; RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes. Cone and solid angle steric parameters for perfluoroalkyl ligands.”, J. Chem. Soc., Dalton Trans. 2000, 873-879.

7

Hughes, R.P.; Smith, J.M. “Hydrogenolysis of Aliphatic Carbon-Fluorine Bonds in Fluoroalkyl-Iridium Complexes to Give Hydrofluorocarbons.”, J. Am. Chem. Soc. 1999, 121, 6084-6085. (featured in Chemtracts – Inorg. Chem. 2000, 13, 796-799.)

6

Taverner, B.C.; Smith, J.M.; White, D.P.; Coville, N.J. “Quantification of Ligand-Ligand Interactions using Solid Angles.”, S. Afr. J. Chem. 1997, 50, 59-66.

5

Smith, J.M.; Taverner, B.C.; Coville, N.J. “Cone Angle Radial Profiles.”, J. Organomet. Chem. 1997, 530, 131-140.

4

Smith, J.M.; Pelly, S.C.; Coville, N.J. “Intramolecular Steric Interactions in [h5-C5H3(SiMe3)2Ru(CO)(L)I] - Analysis by Radial Profiles.”, J. Organomet. Chem. 1996, 525, 159-166.

3

Smith, J.M.; Coville, N.J. “Analysis of Stereochemical Non-Rigidity in Five-Coordinate Cyclopentadienyl Complexes by the Structure Correlation Method.”, Organometallics 1996, 15, 3388-3392.

2

Smith, J.M.; White, D.; Coville, N.J. “Substituted Cyclopentadienyl Ligands 11. Intramolecular Steric Interactions in [(h 5-C5H4(SiMe3))Mo(CO)2(L)I].”, Bull. Chem. Soc. Ethiop. 1996, 10, 1-8.

1

Smith, J.M; White, D.P.; Coville, N.J. “Substituted Cyclopentadienyl Ligands 10. Intramolecular Steric Interactions in [(h 5-C5H3(SiMe3)2)Mo(CO)2(L)I].”, Polyhedron 1996, 15, 4541-4554.